Catalytic alkene cyclohydroamination via an imido mechanism.
نویسندگان
چکیده
Chiral-at-metal half-sandwich diamide complexes catalyse enantioselective cyclohydroamination of aminoalkenes at unexpectedly high rates given their high coordination number and steric bulk; substantial evidence is presented which argues against the established sigma-bond insertion process and is strongly indicative of an imido [2+2] cycloaddition mechanism.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 12 شماره
صفحات -
تاریخ انتشار 2008